The following classes of chemicals tend to form peroxides upon aging.
Class I
- Unsaturated materials, especially those of low molecular weight, may polymerize violently and hazardously due to peroxide initiation.
| acrylic acid | styrene |
| acrylonitrile | tetrafluoroethylene |
| 1,3-butadiene | vinyl acetate |
| 2-chloro-1,3-butadiene (chloroprene) | vinyl acetylene |
| chlorotrifluoroethylene | vinyl chloride |
| 1,1-dichloroethene | vinyl pyridine |
| methyl methacrylate | vinylidene chloride |
Class II
- The following chemicals are a peroxide hazard upon concentration (distillation/evaporation). A test for peroxides should be performed if concentration is intended or suspected.
| acetal | ethylene glycol dimethyl ether (glyme) |
| cyclohexene | furan |
| cyclooctene | isopropyl benzene |
| cyclopentene | methylacetylene |
| diacetylene | methylcyclopentane |
| dicyclopentadiene | methylisobutyl ketone |
| diethylene glycol dimethyl ether (diglyme) | tetrahydrofuran |
| diethyl ether | tetrahydronaphthalene |
| dioxane (p-dioxane) | vinyl ethers |
Class III
- Peroxides derived from the following compounds may explode without concentration.
| divinyl ether | potassium metal |
| divinyl acetylene | potassium amide |
| diisopropyl ether | sodium amide |
| 1,1-dichloroethene |

