APPENDIX XI - PEROXIDE FORMING CHEMICALS

November 1996

The following classes of chemicals tend to form peroxides upon aging.

Class I

- Unsaturated materials, especially those of low molecular weight, may polymerize violently and hazardously due to peroxide initiation.

acrylic acid styrene
acrylonitrile tetrafluoroethylene
1,3-butadiene vinyl acetate
2-chloro-1,3-butadiene (chloroprene) vinyl acetylene
chlorotrifluoroethylene vinyl chloride
1,1-dichloroethene vinyl pyridine
methyl methacrylate vinylidene chloride

Class II

- The following chemicals are a peroxide hazard upon concentration (distillation/evaporation). A test for peroxides should be performed if concentration is intended or suspected.

acetal ethylene glycol dimethyl ether (glyme)
cyclohexene furan
cyclooctene isopropyl benzene
cyclopentene methylacetylene
diacetylene methylcyclopentane
dicyclopentadiene methylisobutyl ketone
diethylene glycol dimethyl ether (diglyme) tetrahydrofuran
diethyl ether tetrahydronaphthalene
dioxane (p-dioxane) vinyl ethers

Class III

- Peroxides derived from the following compounds may explode without concentration.

divinyl ether potassium metal
divinyl acetylene potassium amide
diisopropyl ether sodium amide
1,1-dichloroethene

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