APPENDIX VII - OSHA PERMISSIBLE EXPOSURE LIMIT

November 1996

A Permissible Exposure Limit (PEL) is a Time Weighted Average (TWA) concentration that must not be exceeded during any 8-hour work shift of a 40-hour work week. A Short Term Exposure Limit (STEL) is measured over a 15-minute period. A "ceiling" concentration must not be exceeded during any part of the workday; if instantaneous monitoring is not feasible, the ceiling must be assessed as a 15-minute TWA exposure. The "skin" designation indicates the potential for dermal absorption; skin exposure should be prevented as necessary through the use of good work practices and gloves, goggles, and other appropriate equipment.

Chemical Name PEL (ppm) PEL (mg/m3) Comment
Acetaldehyde 200 360
Acetic acid 10 25
Acetone 1000 2400
Acetonitrile 40 70
STEL 60 105
Acrolein 0.1 0.25
STEL 0.3 0.69
Acrylamide 0.3 skin
Acrylonitrile 2
Ammonia (anhydrous) 35 27
Ammonium hydroxide 35 27
Aniline 5 19 skin
Arsine 0.05 0.2
Benzene 1 3.2
Boron trifluoride 1 3 ceiling
Bromine 0.1
Carbon disulfide 4 12
STEL 12 36 skin
Carbon monoxide 50 55
Carbon tetrachloride 2 13
Chlorine 1 3
Chloroform 50 240 ceiling
Chromium trioxide 0.1 ceiling
Diazomethane 0.2 0.4
Diborane 0.1
Dichloromethane 500
Diethyl ether 400
Dimethyl sulfate 1 5 skin
Dimethylformamide 10 30 skin
Dioxane 100 360 skin
Ethanol 1000 1900
Ethyl acetate 400 1400
Ethylene dibromide 20 150
Ethylene oxide 1 2
Fluorides (inorganic) 2.5
Fluorine 0.1 0.2
Formaldehyde 1 1.5
STEL 2 2.5
Hexane 500 1800
Hydrazine 1 1.3 skin
Hydrobromic acid 3 10
Hydrochloric acid 5 7 ceiling
Hydrogen cyanide 10 11 skin
Hydrogen fluoride 3
Hydrofluoric acid 3
Hydrogen peroxide 1 1.4
Hydrogen sulfide 20 28 ceiling
Iodine 0.1 1 ceiling
Lead 0.05
Mercury 0.1 ceiling
Methanol 200 260
Methyl ethyl ketone 200 590
Methyl iodide 5 28 skin
Nickel carbonyl 0.001 0.007
Nitric acid 2 / 5
Nitrogen dioxide 5 / 9 - ceiling
Osmium tetroxide 0.0002 0.002
Ozone 0.1 0.2
Phenol 5 19 skin
Phosgene 0.1 0.4
Phosphorus 0.1
Potassium hydroxide 2
Pyridine 5 15
Silver 0.01
Sodium hydroxide 2
Sulfur dioxide 5 13
Sulfuric acid 1
Tetrahydrofuran 200 590
Toluene 200 750
STEL 150 560
Toluene diisocyanate 0.02 0.14 ceiling
Trimethyltin chloride 0.1 mg of tin

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